Cement & Properties

What is concrete?

Concrete is not found in nature the way we would find aluminium, nickel or iron. Concrete is formed from combining water, a special cement and rock: PORTLAND CEMENT + H2O + ROCK = HARDENED CONCRETE + ENERGY(HEAT)
A common mistake people make is to use the words cement and concrete interchangably. It is important to remember that cement is only a component of concrete and concrete is the structural material. The cement used in concrete is not used as a building material because it would be too expensive and not as strong as concrete. So when you see a parking garage, a driveway, a sidewalk or a road remember it is made of concrete, not cement. And, by the way, that funny looking truck is a concrete mixer, not a cement mixer! But, if cement is not concrete, then what is it?
Cement is a general name for a material that binds other materials together. Yes, it is another name for glue. There are many materials which we would classify as cements and they are usually identified with certain uses, and can produce different types of "concrete". The type of cement used to make the riding surface of some of our roads (blacktop!) is called asphalt cement. It is a petroleum bi-product, and it binds rock into the road material we call asphaltic concrete.
Adding water to the dry cement starts a chemical reaction (hydration). While the mixture of cement, water, and rock is fluid, it can be poured into molds (called formwork) of arbitrary shape. This is a valuable property of concrete which allows us to build dams with the many different shapes which you saw in the history of dams. The compound gradually hardens into the desired final shape. The water/cement ratio (w/c) of the mixture has the most control over the final properties of the concrete. The water/cement ratio is the relative weight of the water to the cement in the mixture. The water/cement ratio is a design criterion for the engineer. Selection of a w/c ratio gives the engineer control over two opposing, yet desirable properties: strength and workability. A mixture with a high w/c will be more workable than a mixture with a low w/c: it will flow easier. But the less workable the mixture, the stronger the concrete will be. The engineer must decide what ratio will give the best result for the given situation. This is not an entirely free choice because the water/cement ratio needs to be about 0.25 to complete the hydration reaction. Typical values of w/c are between 0.35 and 0.40 because they give a good amount of workability without sacrificing a lot of strength.
	The other important component for strength is the aggregate, the rock that is being bound by the hardened cement. Aggregate is what makes the difference between hardened cement and the structual material, concrete. Aggregate increases the strength of concrete and is a fundamental economical factor because it takes up a large volume of the concrete and is much less expensive than an equivlant volume of cement. To make very strong concrete requires a low w/c and strong aggregate. There might be thousands or millions of tons of cement and aggregate in a large dam. Finding the aggregate for the dam, and transporting it and the cement to the dam site are important societal factors.

Properties of concrete

Concrete has relatively high compressive strength, but significantly lower tensile strength, and as such is usually reinforced with materials that are strong in tension (often steel). The elasticity of concrete is relatively constant at low stress levels but starts decreasing at higher stress levels as matrix cracking develops. Concrete has a very low coefficient of thermal expansion, and as it matures concrete shrinks. All concrete structures will crack to some extent, due to shrinkage and tension. Concrete which is subjected to long-duration forces is prone to creep.

Tests can be made to ensure the properties of concrete correspond to specifications for the application.The density of concrete varies, but is around 2,400 kg/m³ (150 pounds per cubic foot or 4,050 lb/yd³).lol= 0870312642}}</ref> As a result, without compensating, concrete would almost always fail from tensile stresses – even when loaded in compression. The practical implication of this is that concrete elements subjected to tensile stresses must be reinforced with materials that are strong in tension.

Reinforced concrete is the most common form of concrete. The reinforcement is often steel, rebar (mesh, spiral, bars and other forms). Structural fibers of various materials are available.

Concrete can also be prestressed (reducing tensile stress) using internal steel cables (tendons), allowing for beams or slabs with a longer span than is practical with reinforced concrete alone. Inspection of concrete structures can be non-destructive if carried out with equipment such as a Schmidt hammer, which is used to estimate concrete strength.The ultimate strength of concrete is influenced by the water-cementitious ratio (w/cm), the design constituents, and the mixing, placement and curing methods employed. All things being equal, concrete with a lower water-cement (cementitious) ratio makes a stronger concrete than that with a higher ratio. The total quantity of cementitious materials (portland cement, slag cement, pozzolans) can affect strength, water demand, shrinkage, abrasion resistance and density. All concrete will crack independent of whether or not it has sufficient compressive strength. In fact, high Portland cement content mixtures can actually crack more readily due to increased hydration rate. As concrete transforms from its plastic state, hydrating to a solid, the material undergoes shrinkage. Plastic shrinkage cracks can occur soon after placement but if the evaporation rate is high they often can actually occur during finishing operations, for example in hot weather or a breezy day. In very high-strength concrete mixtures (greater than 70 MPa) the crushing strength of the aggregate can be a limiting factor to the ultimate compressive strength. In lean concretes (with a high water-cement ratio) the crushing strength of the aggregates is not so significant.

The internal forces in common shapes of structure, such as arches, vaults, columns and walls are predominantly compressive forces, with floors and pavements subjected to tensile forces. Compressive strength is widely used for specification requirement and quality control of concrete. The engineer knows his target tensile (flexural) requirements and will express these in terms of compressive strength.Wired.com reported on April 13, 2007 that a team from the University of Tehran, competing in a contest sponsored by the American Concrete Institute, demonstrated several blocks of concretes with abnormally high compressive strengths between 340 and 410 MPa (49,000 and 59,000 psi) at 28 days. The blocks appeared to use an aggregate of steel fibres and quartz – a mineral with a compressive strength of 1100 MPa, much higher than typical high-strength aggregates such as granite (100–140 MPa or 15,000–20,000 psi).

Reactive Powder Concrete, also known as Ultra-High Performance Concrete, can be even stronger, with strengths of up to 800 MPa (116,000 PSI). These are made by eliminating large aggregate completely, carefully controlling the size of the fine aggregates to ensure the best possible packing, and incorporating steel fibers (sometimes produced by grinding steel wool) into the matrix. Reactive Powder Concretes may also make use of silica fume as a fine aggregate. Commercial Reactive Powder Concretes are available in the 170–210 MPa (25,000–30,000 psi) strength range.